While Angelina Jolie made a name for herself in Hollywood with her beauty and talent, it was her off-camera work that got our attention. The 42-year-old mother of six (including three adopted children) served for years as a United Nations Goodwill Ambassador. She was later appointed as a special envoy focusing on refugee displacement on a global level, traveling abroad to find solutions to problems refugees face. In her spare time (how does she have any?), she also produces and directs.